Advances in the Determination of Pesticide Residues in Vegetables
WANG Xiao-fei, ZHOU Qi-xing
1. Key Laboratory of Terrestrial Ecological Process, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016; 2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
The present analytical methods and determining techniques, pre-treatment processes of samples, and the rapid and easily determination of pesticides remaining in vegetables were reviewed. Solid-phase extraction, supercritical fluid extraction and other new methods have replacing the traditional method such as liquid-liquid extraction. Chromatography techniques are of great importance in detection of pesticide residues. At present, capillary gas chromatography, high performance liquid chromatography and the combined techniques are the major analytical methods though other new methods exist. The method of rapid determination of pesticides was also presented.
王晓飞, 周启星*. 蔬菜中农药残留检测技术研究进展[J]. , 2004, 23(4): 356-361.
WANG Xiao-fei, ZHOU Qi-xing. Advances in the Determination of Pesticide Residues in Vegetables. , 2004, 23(4): 356-361.
[20] Barker S A.1989.Matrix solid-phase dispersion[J].J Chromatogr A, 475(1):353-361.
[21] Beltran J, López F L, Hernóndez F.2000.Solid-phase mircoextraction in pesticide residue analysis[J].J Chromtogr A, 885:389-404.
[22] Fernóndez M, Picó M, MaNes J.2000.Determination of carbomate residues in fruits and vegetables by matrix solid-phase dispension and liquid chromatography-mass spectrometry [J].J ChromatogrA, 871:43-56.
[23] Font Y G, Moltó J M, et al.2000.Pesticide residue determination in fruit and vegetables by liquid chromatography-mass spectrometry[J].J Chromtogr A,882:153-173.
[24] Gogol E V, Evtyugin G A, Suprun E V, et al.2001.Determination of residual pesticide in plant materials using planarcholinesterase Sensors modified with Nafion[J].Joural of analytical chemisty,(10):963-970.
[25] Hopper M L.1997.Extraction and cleanup oforganochlorine and organophosphorus pesticide residue in fats by supercritical fluid techniques[J].AOAC Int, 80(3):639-646.
[26] Mukherjee I, Gopal M.1996.Chromatographic techniques in the analysis of organochlorine pesticide residues[J].J Chromtogr A, 754:33-42.
[27] Lehotay S J, Aharonson N, Pfeil E, et al.1995.Librahim development of a sample preparation technique for supercritical fluid extraction for multiresidue analysis of pesticides in produce[J].AOAC Int, 78(3):831.
[28] Liang J, Zhou Q.2003.Single and binary-combined toxicity of methamidophos, acetochlor and copper acting on earthworms Esisenia Foelide[J].Bulletin of Environmental Contamination and Toxicology, 71(6):1158-1166.
[29] Liu J.1998.Solide-phase microextraction(SPME) of drugs and poisons from biological samples[J].Forensic Science International,(97):93-100.
[30] Pacáková V, Jiskra K J, Jiskra.1996.High-performance separations in the determination of triazine herbicides and their residues[J].J Chromtogr A, 754:301-331.
[31] Sannino A, Mambriani P, Bandini M.1995.Multiresidue method for determination of organophosphorus insecticide residues in fatty processed foods by gel permeation chromatography[J].AOA C Int, 78(6):1502-1512.
[32] Terres C M, Pico Y, Manes J.1996.Determination of pesticide residues in fruits and vegetables [J].J Chromtogr A,754:17-31.
[33] Valvede-Garcia, Gonzalez-Pradas E, Aguileradel-Real.1993.Application to the degradation study on eggplant grown in a greenhouse[J].Agric Food:Chem, 41(12) 2319-2323.
[34] Yu Y, Zhou Q.2003.Effect of methamidophos on sorption-desorption behavior of copper in soils[J].Bulletin of Environmental Contamination and Toxicology, 71(5):979-987.
[35] Zhang H, Zhang Q, Zhou Q, Zhang C.2003.Binary-joint effects of acetochlor, methamidophos, and copper on soil microbial population[J].Bulletin of Environmental Contamination and Toxicology, 71(4):746-754.