石油添加剂甲基叔丁基醚的污染治理技术研究进展

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摘要

甲基叔丁基醚是一种石油添加剂,广泛应用于中高档汽油中.其对环境造成的污染和对人体健康造成的危害已日益引起人们的高度重视.本文综述了近年来国外有关甲基叔丁基醚的污染治理技术研究进展,主要是高级氧化技术和微生物降解.已用于处理甲基叔丁基醚的高级氧化技术包括;多相光催化氧化法、紫外光加强的过氧化氢氧化法、臭氧法与臭氧-过氧化氢联合氧化法、超声法与超声-臭氧联合氧化法、芬顿法与光芬顿氧化法、氧气的还原性活化和水的γ射线辐射.微生物降解主要涉及有氧代谢和无氧代谢两大途径.

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	徐向荣
	顾继东

关键词 ：甲基叔丁基醚, 污染治理技术, 高级氧化技术

Abstract：

Methyl tert-butyl ether is a widely used gasoline additive.Its presence in the environment causes a widespread pollution and poses a serious threat to human health.Current literature on the treatments of methyl tert-butyl ether contamination,including advanced oxidation processes and microbial biodegradation,is reviewed.The advanced oxidation technologies include heterogeneous photocatalytic oxidation,UV/H₂O₂ oxidation,conventional ozonation and ozone/hydrogen peroxide,ultrasound irradiation and sonolytic degradation in the presence of ozone,Fenton's reagent and UV-assisted Fenton's reagent,reductive activation of dioxygen as well as r radiolysis of H₂O.Microbial biodegradation of MTBE involves both the aerobic and anaerobic metabolism.

Key words： Methyl tert-butyl ether Treatment Contamination Advanced oxidation technologies Microbial biodegradation

收稿日期: 2003-04-25

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引用本文:

徐向荣, 顾继东. 石油添加剂甲基叔丁基醚的污染治理技术研究进展[J]. , 2003, 22(2): 177-182.
XU Xiang-rong, GU Ji-dong. Study Progress on Treatments of the Gasoline Additive Methyl tert-Butyl Ether Contamination. , 2003, 22(2): 177-182.

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http://www.ecolsci.com/CN/Y2003/V22/I2/177

[1] Acero J L, Haderlein S B, Schmidt T C, et al. 2001. MTBE oxidation by conventional ozonation and the combination ozone/hydrogen peroxide:Efficiency of the processes and bromate formation [J]. Environmental Science & Technology,35(21):4252～4259.

[2] Ahmed F E. 2001. Toxicology and human health effects following exposure to oxygenated or reformulated gasoline[J]. Toxicology Letters, 123(2-3):89～113.

[4] Annesini M C, Gironi F & Monticelli B. 2000. Removal of oxygenated pollutants from wastewater by polymeric resins:Data on adsorption equilibrium and kinetics in fixed beds [J].Water Research, 34(11):2989～2996.

[5] Barreto R D, Gray K A & Anders K. 1995. Photocatalytic degradation of methyl tert-butyl ether in TiO2 slurries-a proposed reaction scheme [J]. Water Research,29(5):1243～1248.

[6] Bradley P M, Chapelle F H & Landmeyer J E. 2001. Effect of redox conditions on MTBE biodegradation in surface water sediments[J]. Environmental Science & Technology, 35(23):4643～4647.

[7] Bradley P M, Chapelle F H & Landmeyer J E. 2001. Methyl tert-butyl ether mineralization in surface-water sediment microcosms under denitrifying conditions [J]. Applied andEnvironmental Microbiology, 67(4):1975～1978.

[8] Burbano A A, Dionysiou D D, Richardson T L, et al. 2002.Degradation of MTBE intermediates using Fenton's reagent[J]. Journal of Environmental Engineering-ASCE,128(9):799-805.

[10] Cater S R, Stefan M I, Bolton J R, et al. 2000. UV/H₂O₂ treatment of methyl tert-butyl ether in contaminated waters[J]. Environmental Science & Technology, 34(4):659～662.

[12] Chang P B L & Young T M. 2000. Kinetics of methyl tert-butyl ether degradation and by-product formation during UV/hydrogen peroxide water treatment [J]. Water Research,34(8):2233～2240.

[13] Damm J H, Hardacre C, Kalin R M, et al. 2002. Kinetics of the oxidation of methyl tert-butyl ether (MTBE) by potassium permanganate [J]. Water Research,36(14):3638～3646.

[14] Deeb R A, Scow K M & Alvarez-Cohen L. 2000. Aerobic MTBE biodegradation:an examination of past studies,challenges and future research directions [J]. Biodegradation,11(2-3):171-186.

[15] Dupasquier D, Revah S & Auria R. 2002. Biofiltration of methyl tert-butyl ether vapors by cometabolism with pentane:modeling and experimental approach [J]. Environmental Science & Technology, 36(2):247～253.

[16] Fortin N Y, Morales M, Nakagawa Y, et al. 2001. Methyl tert-butyl ether (MTBE) degradation by a microbial consortium [J]. Environmental Microbiology, 3(6):407～416.

[17] Francois A, Mathis H, Godefroy D, et al. 2002.Biodegradation of Methyl tert-butyl ether and other fuel oxygenates by a new strain, Mycobacterium austroafricanum IFP 2012 [J]. Applied and Environmental Microbiology,68(6):2754～2762.

[18] Gamier P M, Auria R, Augur C, et al. 1999. Cometabolism biodegradation of methyl tert-butyl ether by pseudomonas aeruginosa grown on pentane [J]. Applied Microbiology and Biotechnology, 51(4):498～503.

[19] Hagg W R and Yao D C C. 1992. Rate constants for reaction of hydroxyl radicals with several drinking water contaminants [J]. Environmental Science & Technology,26(5):1005～1013.

[20] Hanson J R, Ackerman C E and Scow K M. 1999.Biodegradation of methyl tert-butyl ether by a bacterial pure culture [J]. Applied and Environmental Microbiology, 65(11):4788～4792.

[21] Hardison L K, Curry A, Ciuffetti L M, et al. 1997.Metabolism of Diethyl ether and cometabolism of methyl tert-butyl ether by a filamentous fungus, a Graphium sp. [J].Applied and Environmental Microbiology, 63(8):3059～3067.

[22] Hatzinger P B, Mcclay K, Vainberg S, et al. 2001.Biodegradation of methyl tert-butyl ether by a pure bacterial culture [J]. Applied and Environmental Microbiology, 67(12):5601～5607.

[23] Hernandez-Perez G, Fayolle F, Vandecasteele J P. 2001.Biodegradation of ethyl tert-butyl ether (ETBE), methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME)by Gordonia terrae [J]. Applied Microbiology and Biotechnology, 55(1):117～ 121.

[24] Huang K C, Couttenye R A & Hoag GE. 2002. Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE) [J]. Chemosphere, 49(4):413～420.

[25] Kang J W & Hoffmann M R. 1998. Kinetics and mechanism of the sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation in the presence of ozone [J].Environmental Science & Technology, 32(20):3194～3199.

[26] Kim D K, O'Shea K E & Cooper W J. 2002. Degradation of MTBE and related gasoline oxygenates in aqueous media by ultrasound irradiation [J]. Journal of Environmental Engineering-ASCE, 128(9):806～812.

[27] Lien H S L & Wilkin R. 2002. Reductive activation of dioxygen for degradation of methyl tert-butyl ether by bifunctional aluminum [J]. Environmental Science &Technology, 36(20):4436～4440.

[28] Lifka J, Hoffmann J & Ondruschka B 2001. Ethers as pollutants in groundwater:the role of reaction parameters during the aquasonolysis [J]. Water Science and Technology,44(5):139～ 144.

[29] Lin S H, Wang C S & Chang C H. 2002. Removal of methyl tert-butyl ether from contaminated water by macroreticular resin [J]. Industrial & Engineering Chemistry Research,41(16):4116～4121.

[30] Liu C Y, Speitel J G E & Georgiou G. 2001. Kinetics of methyl tert-butyl ether cometabolism at low concentrations by pure cultures of butane-degrading bacteria [J]. Applied and Environmental Microbiology, 67(5):2197～2201.

[31] Mitani M M, Keller A A, Bunton C A, et al. 2002. Kinetics and products of reactions of MTBE with ozone and ozone/hydrogen peroxide in water [J].Journal of Hazardous Materials, 89(2-3):197～212.

[32] Mo K, Lora C O, Wanken A E, et al. 1997. Biodegradation of methyl t-butyl ether by pure bacterial cultures [J]. Applied Microbiology and Biotechnology, 47(1):69～72.

[33] Neppolian B, Jung H, Choi H, et al. 2002. Sonolytic degradation of methyl tert-butyl ether:the role of coupled Fenton process and persulphate ion [J]. Water Research,36(19):4699～4708.

[34] Safarzadeh-Amiri A. 2001. O3/H₂O₂ treatment of methyl-tert-butyl ether (MTBE) in contaminated waters [J]. Water Research, 35(15):3706～3714.

[35] Sahle-Demessie E, Richardson T, Almquist C B, et al. 2002.Comparison of liquid and gas phase photooxidation of MTBE:Synthetic and field samples [J]. Journal of Environmental Engineering-ASCE, 128 (9):782～790.

[36] Sahle-Demessie E, Enriquez J & Gupta G. 2002. Attenuation of methyl tert-butyl ether in water using sunlight and aphotocatalyst [J]. Water Environment Research,74(2):122～130.

[37] Salanitro J P, Diaz L A, Williams M P, et al. 1994. Isolation of a bacterial culture that degrades methyl t-butyl ether [J].Applied and Environmental Microbiology, 60(7):2593～2596.

[38] Shih T C, Wangpaichitr M & Suffet M. 2003. Evaluation of granular activated carbon technology for the removal of methyl tertiary butyl ether (MTBE) from drinking water [J].Water Research, 37(2):375～385.

[39] Smith C A, O'Reilly K T, Hyman M R. 2003.Characterization of the initial reactions during the cometabolic oxidation of methyl tert-butyl ether by propane-grown Mycobacterium vaccae JOB5 [J].Applied and Environmental Microbiology, 69(2):796～804.

[40] Somsamak P, Cowan R M and Haggblom M M. 2001.Anaerobic biotransformation of fuel oxygenates under sulfate-reducing conditions [J]. FEMS Microbiology Ecology, 37(3):259～264.

[41] Steffan R J, Simon V K M, Condee C W, et al. 1997.Biodegradation of gasoline oxygenates methyl tert-butyl ether, ethyl tert-butyl ether and tert-amyl methyl ether other by propane-oxidizing bacteria [J]. Applied and Environmental Microbiology, 63 (11):4216～4222.

[42] Stefan M I, Mack J & Bolton J R. 2000. Degradation pathways during the treatment of methyl tert-butyl ether by the UV/H₂O₂ process [J]. Environmental Science & Technology, 34(4):650～658.

[43] Weinstock I A, Barbuzz E M G, Wemple M W, et al. 2001.Equilibrating metal-oxide cluster ensembles for oxidation reactions using oxygen in water [J]. Nature, 414(6860):191～195.

[44] Wilhelm M J, Adams V D, Curtis J G, et al. 2002. Carbon adsorption and air-stripping removal of MTBE from river water [J]. Journal of Environmental Engineering ASCE,128(9):813～823.

[45] Wu T X, Cruz V, Mezyk S, et al. 2002. Gamma radiolysis of methyl t-butyl ether:a study of hydroxyl radical mediated reaction pathways [J]. Radiation Physics and Chemistry,65(4-5):335～341.

[46] Yeh C K & Novak J T. 1995. The effect of hydrogen peroxide on the degradation of methyl and ethyl tert-butyl ether in soils [J]. Water Environment Research, 67(5):828～834.

[47] Yeh C K & Novak J T. 1994. Anaerobic biodegradation of gasoline oxygenates in soils [J]. Water Environment Research, 66(5):744～752.